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Note that the resulting Arnold Material won't be a perfect match to the C4D Material since Arnold has different shaders and concepts. See the Cinema 4D Material page for the supported features and limitations.

Default shortcut is Alt+W~C in the Material Browser.

Replace the Selected C4D Material with an Arnold Material

Creates a new Arnold Material with the shader network converted from the selected C4D Material and replaces the original C4D Material in the scene with the new Arnold Material.